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新加坡对26种化学物质实施管制许可

信息来源:瑞旭集团    发布日期:2022-11-18    阅读:1783次
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2022年11月消息,新加坡国家环境局(NEA)已根据《环境保护与管理法》(EPMA),将26种化学物质列为有害物质(hazardous substances, HS)进行管制,从事涉及26种化学品中任何一种的以下活动的公司必须获得HS许可证/执照:

进口、出口、制造、销售、运输、储存和/或使用受管制化学品——需要执照(HS licence);

购买、储存和/或使用受管制化学品——需要许可证(HS permit)。

NEA计划监管于2023年6月生效,这些变化将在2022年12月前通报。自2023年1月1日起,在《环境保护与管理法》和《环境保护和管理(有害物质)条例》修正案公布后,NEA建议公司可开展修改或申请HS许可证/执照。

NEA管制的HS具有高度毒性、污染性,并且是难以进行生产管理和安全处置的废料。

对于具有更广泛工业用途的物质,NEA正在对这些物质构成的潜在安全和环境风险进行更详细的审查,以便在可能的情况下给予低浓度豁免。利益相关方可以在2022年11月 10日之前将相关数据(例如安全数据表、混合物/产品中存在的化学品浓度以及化学品储量)提交NEA进行审议。

目前,这26种化学物质由新加坡海关根据《化学武器(禁止)法》(CWPA)和《化学武器(禁止)条例》(CWPR)与NEA共同监管。

26种化学物质清单:

S/N

Chemical Name

CAS Registry No.

1

O-Alkyl(≤C10, including cycloalkyl) alkyl (Me, Et, n-Pr or i-Pr)-phosphonofluoridates

e.g.

Sarin: O-Isopropyl methylphosphonofluoridate

Soman: O-Pinacolyl methylphosphonofluoridate

107-44-8

96-64-0

2

O-Alkyl (H or ≤C 10 , including cycloalkyl) S-2-dialkyl (Me, Et, n-Pr or i-Pr)-aminoethyl alkyl (Me, Et, n-Pr or i-Pr) phosphonothiolates and corresponding alkylated or protonated salts

e.g.

VX: O-Ethyl S-2-diisopropylaminoethyl methyl phosphonothiolate

50782-69-9

3

Lewisites:

Lewisite 1: 2-Chlorovinyldichloroarsine

Lewisite 2: Bis(2-chlorovinyl)chloroarsine

Lewisite 3: Tris(2-chlorovinyl)arsine

541-25-3

40334-69-8

40334-70-1

4

Nitrogen mustards:

HN1: Bis(2-chloroethyl)ethylamine

HN2: Bis(2-chloroethyl)methylamine 51-75-2

HN3: Tris(2-chloroethyl)amine

538-07-8

51-75-2

555-77-1

5

Saxitoxin

35523-89-8

6

Ricin

9009-86-3

7

Alkyl (Me, Et, n-Pr or i-Pr) phosphonyl difluorides

e.g.

DF: Methylphosphonyldifluoride

676-99-3

8

O-Alkyl (H or ≤C 10 , including cycloalkyl) O-2-dialkyl (Me, Et, n-Pr or i-Pr)-aminoethyl alkyl (Me, Et, n-Pr or i-Pr)-phosphonites and

corresponding alkylated or protonated salts

e.g.

QL: O-Ethyl O-2-diisopropylaminoethyl methylphosphonite

57856-11-8

9

Chlorosarin: O-Isopropyl methylphosphonochloridate

1445-76-7

10

Chlorosoman: O-Pinacolyl methylphosphonochloridate

7040-57-5

11

Р-alkyl (H or ≤C 10 , incl. cycloalkyl) N-(1-(dialkyl(≤C 10 , incl.cycloalkyl)amino))alkylidene(H or ≤C 10 , incl. cycloalkyl)

phosphonamidic fluorides and corresponding alkylated or protonated salts

e.g.

N-(1-(di-n-decylamino)-n-decylidene)-P-decylphosphonamidic fluoride 2387495-99-8

Methyl-(1-(diethylamino)ethylidene) phosphonamidofluoridate

2387495-99-8

2387496-12-8

12

O-alkyl (H or ≤C 10 , incl. cycloalkyl) N-(1-(dialkyl(≤C 10 , incl. cycloalkyl)amino))alkylidene(H or ≤C 10 , incl. cycloalkyl)

phosphoramidofluoridates and corresponding alkylated or protonated salts

e.g.

O-n-Decyl N-(1-(di-n-decylamino)-ndecylidene)

phosphoramidofluoridate

Methyl (1-(diethylamino)ethylidene) phosphoramidofluoridate

Ethyl (1-(diethylamino)ethylidene) phosphoramidofluoridate

2387496-00-4

2387496-04-8

2387496-06-0

13

Methyl-(bis(diethylamino)methylene) phosphonamidofluoridate

2387496-14-0

14

Carbamates (quaternaries and bisquaternaries of

dimethylcarbamoyloxypyridines)

Quaternaries of dimethylcarbamoyloxypyridines:

1-[N,N-dialkyl(≤C10)-N-(n-(hydroxyl, cyano, acetoxy)alkyl(≤C10)) ammonio]-n-[N-(3-dimethylcarbamoxy-α-picolinyl)-N,N dialkyl(≤C10) ammonio]decane dibromide (n=1-8)

e.g.

1-[N,N-dimethyl-N-(2-hydroxy)ethylammonio]-10 [N- (3-dimethylcarbamoxy-α-picolinyl)-N,N dimethylammonio]decane dibromide

Bisquaternaries of dimethylcarbamoyloxypyridines:

1,n-Bis[N-(3-dimethylcarbamoxy-α-picolyl)-N,N-dialkyl(≤C10)ammonio]-alkane-(2,(n-1)-dione) dibromide (n=2-12)

e.g.

1,10-Bis[N-(3-dimethylcarbamoxy-α picolyl)-N-ethyl-N-methylammonio] decane-2,9-dione dibromide

77104-62-2

77104-00-8

15

PFIB: 1,1,3,3,3-Pentafluoro-2-(trifluoromethyl) -1-propene

382-21-8

16

BZ: 3-Quinuclidinyl benzilate

6581-06-2

17

Chemicals, except for those listed in Schedule 1, containing a phosphorus atom to which is bonded one methyl, ethyl or propyl (normal or iso) group but not further carbon atoms

e.g.

Methylphosphonyl dichloride

Dimethyl methylphosphonate

Exemption:

Fonofos: O-Ethyl S-phenyl ethylphosphonothiolothionate

676-97-1

756-79-6

944-22-9

18

Dialkyl (Me, Et, n-Pr or i-Pr) N,N-dialkyl (Me, Et, n-Pr or i-Pr)- phosphoramidates

-

19

2,2-Diphenyl-2-hydroxyacetic acid: Benzilic acid

76-93-7

20

Quinuclidin-3-ol

1619-34-7

21

N,N-Dialkyl (Me,Et,n-Pr or i-Pr) aminoethyl- 2-chlorides and corresponding protonated salts

-

22

N,N-Dialkyl (Me, Et, n-Pr or i-Pr) aminoethane-2-thiols and corresponding protonated salts

-

23

Thiodiglycol: Bis(2-hydroxyethyl)sulfide

111-48-8

24

Diethyl phosphite

762-04-9

25

Thionyl chloride

7719-09-7

26

Triethanolamine

102-71-6

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